Gas-phase atmospheric chemistry of organic compounds emitted from anthropogenic and biogenic sources. This includes the experimental investigation of the kinetics, products, and mechanisms of the gas-phase reactions of organic compounds with hydroxyl (OH) radicals, nitrate (NO3) radicals and ozone (O3). Much of the focus is now on the products and mechanisms of these reactions, using gas chromatography, in situ Fourier transform infrared spectroscopy, and in situ atmospheric pressure ionization tandem mass spectrometry for product analyses.
1.1 OH + Alkanes and Cycloalkanes (February 2003)
1.6 OH + Phosphorus-Containing Compounds
Alvarado, A., E. C. Tuazon, S. M. Aschmann, J. Arey and R. Atkinson
1999. Products and Mechanisms of the Gas-Phase Reactions of OH Radicals and O3 with 2-Methyl-3-buten-2-ol. Atmos. Environ., 33, 2893-2905.
Aschmann, S. M. and R. Atkinson
1999. Products of the Gas-Phase Reactions of the OH Radical with n-Butyl Methyl Ether and 2-Isopropoxyethanol: Reactions of ROC(O)< Radicals. Int. J. Chem. Kinet., 31, 501-513.
Atkinson, R., R. Guicherit, R. A. Hites, W.-U. Palm, J. N. Seiber and P. de Voogt
1999. Transformations of Pesticides in the Atmosphere - a State-of-the-Art. Water, Air & Soil Pollut., 115, 195-218.
Atkinson, R.
2000. Atmospheric Chemistry of VOCs and NOx. Atmos. Environ., 34, 2063-2101.
Aschmann, S. M., J. Arey and R. Atkinson
2000. Atmospheric Chemistry of Selected Hydroxycarbonyls. J. Phys. Chem. A, 104, 3998-4003.
Bethel, H. L., R. Atkinson and J. Arey
2000. Products of the Gas-Phase Reactions of OH Radicals with p-Xylene and 1,2,3- and 1,2,4-Trimethylbenzene: Effect of NO2 Concentration. J. Phys. Chem. A, 104, 8922-8929.
Arey, J., S. M. Aschmann, E. S. C. Kwok and R. Atkinson
2001. Alkyl Nitrate, Hydroxyalkyl Nitrate, and Hydroxycarbonyl Formation from the NOx-Air Photooxidations of C5-C8 n-Alkanes. J. Phys. Chem. A, 105, 1020-1027.
Undergraduate course
Graduate courses
Graduate students are from the Interdepartmental Graduate Program in Environmental Toxicology and the Chemistry Department.